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Two-dimensional materials are 00:00
crystalline substances with a thickness 00:02
of a few atoms or less. 00:05
The most famous of the 2D materials is graphene. 00:09
A single layer of carbon atoms called a monolayer, 00:13
which is hundreds of times stronger than steel, 00:16
conducts electricity better than copper, 00:20
and is completely flexible. 00:24
Beyond graphene there exists a host of 2D materials 00:29
with a wide range of different properties. 00:32
One group called transition metal dichalcogenides, 00:35
and known as TMDs, 00:39
combine the incredible thinness of graphene 00:41
with exceptional semiconductor properties. 00:44
Unlike graphene, a TMD monolayer is three atoms thick. 00:47
Each sheet consists of a layer of transition metal atoms, 00:52
such as molybdenum 00:56
or tungsten, 00:58
between two planes of chalcogen atoms, 00:59
such as sulfur 01:02
or selenium. 01:03
TMD monolayers are direct bandgap semiconductors, 01:06
meaning they strongly emit light 01:11
when excited electrically or optically. 01:13
But for thicker TMD sheets such as bilayers 01:16
and trilayers 01:20
the bandgap is indirect and 01:22
the excellent luminescence properties are lost. 01:24
So, to utilise light emission from TMDs 01:27
individual monolayers must be isolated from a bulk crystal. 01:32
To do this researchers at the University of Sheffield 01:36
use a method known as mechanical exfoliation. 01:40
Although atoms within an individual layer 01:47
are strongly bonded to one another, 01:50
adjacent sheets are bound together very weakly 01:52
through the van der Waals interaction. 01:55
By simply applying sticky tape to the crystal 02:10
this weak interlayer bonding can be broken 02:13
and thin films of material 02:15
can be removed from the crystal surface. 02:17
By then applying this tape onto a substrate, 02:21
such as glass, and slowly peeling it back off 02:23
interlayer bonding between layers 02:27
within the thin films can be broken further 02:29
and single monolayers can be 02:32
transferred onto the surface. 02:34
Assembling different 2D materials into vertical stacks, 02:40
one layer at a time, 02:43
creates new artificial materials 02:44
called van der Waals heterostructures. 02:46
By careful control of the sheet order 02:50
within the heterostructure 02:52
the properties of each individual layer can be combined 02:54
to produce optoelectronic devices 02:57
with tailor-made properties. 03:00
This allows the construction of 03:03
electroluminescent devices 03:05
for light-emitting applications, 03:08
as well as photodetectors 03:16
for optical imaging sensors, 03:19
and 2D material transistors 03:25
for the basis of flexible computational elements. 03:30
Combining these different 03:34
electrical and optical elements 03:35
based upon van der Waals heterostructures 03:37
has incredible potential for 03:40
the development of new flexible 03:42
electronic devices that could 03:44
revolutionize current technology. 03:46

– English Lyrics

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Lyrics & Translation

[English]
Two-dimensional materials are
crystalline substances with a thickness
of a few atoms or less.
The most famous of the 2D materials is graphene.
A single layer of carbon atoms called a monolayer,
which is hundreds of times stronger than steel,
conducts electricity better than copper,
and is completely flexible.
Beyond graphene there exists a host of 2D materials
with a wide range of different properties.
One group called transition metal dichalcogenides,
and known as TMDs,
combine the incredible thinness of graphene
with exceptional semiconductor properties.
Unlike graphene, a TMD monolayer is three atoms thick.
Each sheet consists of a layer of transition metal atoms,
such as molybdenum
or tungsten,
between two planes of chalcogen atoms,
such as sulfur
or selenium.
TMD monolayers are direct bandgap semiconductors,
meaning they strongly emit light
when excited electrically or optically.
But for thicker TMD sheets such as bilayers
and trilayers
the bandgap is indirect and
the excellent luminescence properties are lost.
So, to utilise light emission from TMDs
individual monolayers must be isolated from a bulk crystal.
To do this researchers at the University of Sheffield
use a method known as mechanical exfoliation.
Although atoms within an individual layer
are strongly bonded to one another,
adjacent sheets are bound together very weakly
through the van der Waals interaction.
By simply applying sticky tape to the crystal
this weak interlayer bonding can be broken
and thin films of material
can be removed from the crystal surface.
By then applying this tape onto a substrate,
such as glass, and slowly peeling it back off
interlayer bonding between layers
within the thin films can be broken further
and single monolayers can be
transferred onto the surface.
Assembling different 2D materials into vertical stacks,
one layer at a time,
creates new artificial materials
called van der Waals heterostructures.
By careful control of the sheet order
within the heterostructure
the properties of each individual layer can be combined
to produce optoelectronic devices
with tailor-made properties.
This allows the construction of
electroluminescent devices
for light-emitting applications,
as well as photodetectors
for optical imaging sensors,
and 2D material transistors
for the basis of flexible computational elements.
Combining these different
electrical and optical elements
based upon van der Waals heterostructures
has incredible potential for
the development of new flexible
electronic devices that could
revolutionize current technology.

Key Vocabulary

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Key Grammar Structures

  • Two-dimensional materials are crystalline substances with a thickness of a few atoms or less.

    ➔ Noun phrase with compound adjective (two-dimensional) + verb 'to be' + complement

    ➔ The phrase 'two-dimensional' functions as a compound adjective describing 'materials'.

  • which is hundreds of times stronger than steel,

    ➔ Relative clause with comparison 'stronger than'

    ➔ The relative clause beginning with 'which' describes the noun 'monolayer', showing comparison in degree of strength.

  • Beyond graphene there exists a host of 2D materials

    ➔ Inverted sentence for emphasis (verb before subject)

    ➔ The structure 'there exists' places the verb before the subject to emphasize existence.

  • Each sheet consists of a layer of transition metal atoms,

    ➔ Verb phrase 'consists of' (phrasal verb expressing composition)

    ➔ The verb phrase 'consists of' means that something is made up of specific parts.

  • TMD monolayers are direct bandgap semiconductors,

    ➔ Linking verb 'to be' connecting subject and complement (classification)

    ➔ 'are' links 'TMD monolayers' with their classification 'semiconductors'.

  • By simply applying sticky tape to the crystal this weak interlayer bonding can be broken

    ➔ Passive voice with modal verb ('can be broken') and participial phrase ('By applying ...')

    ➔ The participial phrase 'By applying...' expresses the method, while 'can be broken' shows possibility in passive voice.

  • Assembling different 2D materials into vertical stacks, one layer at a time, creates new artificial materials

    ➔ Gerund phrase as subject ('Assembling ... creates ...')

    ➔ The gerund 'Assembling' functions as the subject of the verb 'creates'.

  • By careful control of the sheet order within the heterostructure the properties of each individual layer can be combined

    ➔ Passive voice with modal ('can be combined') + prepositional phrase ('By careful control ...')

    ➔ The structure 'can be combined' expresses possibility, and 'By careful control...' indicates the manner or means.

  • This allows the construction of electroluminescent devices for light-emitting applications,

    ➔ Verb 'allow' + object + infinitive/noun phrase (causative use)

    ➔ The verb 'allows' introduces a causative meaning, showing that one thing makes another possible.

  • has incredible potential for the development of new flexible electronic devices

    ➔ Noun phrase with 'has' (possession) + prepositional phrase ('for ...') expressing purpose

    ➔ 'has incredible potential' expresses possession of capability, while 'for the development...' defines purpose.

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